Ordained Priest | Years | Name | Current Title |
| Most Senior |
| 22 Sep 1945 |
| Bishop Abel Costas Montańo | Bishop Emeritus of Tarija |
| 28 Nov 1948 |
| Archbishop René Fernández Apaza | Archbishop Emeritus of Cochabamba |
| 20 Dec 1952 |
| Bishop Bernardino Rivera Alvarez, O.F.M. | Auxiliary Bishop Emeritus of Potosí |
| 25 Dec 1952 |
| Bishop Manuel Revollo Crespo, C.M.F. | Coadjutor Bishop Emeritus of Bolivia, Military |
| 13 Mar 1954 |
| Bishop Manuel Eguiguren Galarraga, O.F.M. | Auxiliary Bishop Emeritus of El Beni o Beni |
| 14 Mar 1954 |
| Bishop Jesús Agustín López de Lama, C.P. | Prelate Emeritus of Corocoro |
| 14 Jul 1957 |
| Archbishop Alfio Rapisarda | Apostolic Nuncio Emeritus to Portugal |
| 29 Jun 1958 |
| Bishop Leonardo Mario Bernacchi, O.F.M. | Vicar Apostolic Emeritus of Camiri |
| 13 Jul 1958 |
| Bishop Adalberto Arturo Rosat, O.F.M. | Prelate Emeritus of Aiquile |
| 11 Jan 1959 |
| Bishop Walter Pérez Villamonte | Bishop Emeritus of Potosí |
| 19 Mar 1960 |
| Archbishop Santos Abril y Castelló | Apostolic Nuncio to Slovenia |
| 30 Oct 1960 |
| Bishop Adhemar Esquivel Kohenque | Bishop Emeritus of Tarija |
| Most Junior |
| 27 Dec 1990 |
| Bishop Jorge Herbas Balderrama, O.F.M. | Prelate of Aiquile |
| 11 Aug 1988 |
| Bishop Ricardo Ernesto Centellas Guzmán | Bishop of Potosí |
| 29 Nov 1987 |
| Bishop Oscar Omar Aparicio Céspedes | Auxiliary Bishop of La Paz |
| 15 Jun 1985 |
| Bishop Krzysztof Bialasik, S.V.D. | Bishop of Oruro |
| 2 Jun 1984 |
| Bishop Stanislaw Dowlaszewicz Billman, O.F.M. Conv. | Auxiliary Bishop of Santa Cruz de la Sierra |
| 24 Aug 1981 |
| Archbishop Giambattista Diquattro | Apostolic Nuncio to Bolivia |
| 5 Aug 1981 |
| Archbishop Luciano Suriani | Apostolic Nuncio Emeritus to Bolivia |
| 20 Jul 1980 |
| Bishop Juan Vargas Aruquipa | Bishop of Coroico |
| 2 Feb 1979 |
| Bishop Bonifacio Antonio Reimann Panic, O.F.M. | Vicar Apostolic of Ńuflo de Chávez |
| 4 Jun 1978 |
| Archbishop Ivo Scapolo | Apostolic Nuncio to Rwanda |
| 18 Jun 1977 |
| Bishop Adolfo Eduardo José Bittschi Mayer | Auxiliary Bishop of Sucre |
| 18 May 1975 |
| Bishop Francisco Focardi Mazzocchi, O.F.M. | Vicar Apostolic of Camiri |