Ordained Priest | Years | Name | Current Title |
| Most Senior |
| 22 Dec 1945 |
| Archbishop Eurico Dias Nogueira | Archbishop Emeritus of Braga, Portugal |
| 26 Mar 1950 |
| Bishop Pedro Luís Guido Scarpa, O.F.M. Cap. | Bishop Emeritus of Ndalatando |
| 20 Jan 1952 |
| Bishop José Francisco Moreira dos Santos, O.F.M. Cap. | Bishop Emeritus of Uije |
| 20 Jul 1952 |
| Bishop Pedro Luís António | Bishop Emeritus of Kwito-Bié |
| 20 Dec 1952 |
| Alexandre Cardinal do Nascimento | Archbishop Emeritus of Luanda |
| 11 Aug 1957 |
| Archbishop Luis María Pérez de Onraita Aguirre | Archbishop Emeritus of Malanje |
| 27 May 1961 |
| Archbishop Félix del Blanco Prieto | Almoner Emeritus of the Office of Papal Charities, Roman Curia |
| 9 Jul 1961 |
| Archbishop Zacarias Kamwenho | Archbishop Emeritus of Lubango |
| 7 Jul 1963 |
| Bishop Eugenio Dal Corso, P.S.D.P. | Bishop of Benguela |
| 14 Jul 1963 |
| Archbishop Francisco Viti | Archbishop Emeritus of Huambo |
| 26 Jul 1964 |
| Bishop Oscar Lino Lopes Fernandes Braga | Bishop Emeritus of Benguela |
| 2 Aug 1966 |
| Archbishop José de Queirós Alves, C.SS.R. | Archbishop of Huambo |
| Most Junior |
| 6 Dec 1998 |
| Bishop Dionísio Hisilenapo | Bishop of Namibe |
| 5 Dec 1998 |
| Bishop Pio Hipunyati | Bishop of Ondjiva |
| 6 Aug 1995 |
| Bishop Zeferino Zeca Martins, S.V.D. | Auxiliary Bishop of Luanda |
| 23 Aug 1992 |
| Bishop Luzizila Kiala | Bishop of Sumbe |
| 29 Dec 1991 |
| Archbishop José Manuel Imbamba | Archbishop of Saurimo |
| 4 Aug 1991 |
| Bishop Emílio Sumbelelo | Bishop of Uije |
| 16 Jun 1991 |
| Bishop José Manuel Garcia Cordeiro | Bishop of Bragança-Miranda, Portugal |
| 29 Sep 1990 |
| Bishop António Francisco Jaca, S.V.D. | Bishop of Caxito |
| 22 Nov 1987 |
| Bishop Estanislau Marques Chindekasse, S.V.D. | Bishop of Dundo |
| 6 Jul 1986 |
| Archbishop Novatus Rugambwa | Apostolic Nuncio to São Tomé and Príncipe |
| 6 Jul 1986 |
| Bishop Almeida Kanda (Canda) | Bishop of Ndalatando |
| 28 Sep 1985 |
| Bishop Jesús Tirso Blanco, S.D.B. | Bishop of Lwena |