Ordained Bishop | Years | Name | Current Title |
| Most Senior |
| 2 Apr 1977 |
| Lubomyr Cardinal Husar, M.S.U. | Major Archbishop Emeritus of Kyiv-Halyč {Kiev} (Ukrainian) |
| 1 Mar 1981 |
| Bishop Innocent Hilarion Lotocky, O.S.B.M. | Bishop Emeritus of Saint Nicolas of Chicago (Ukrainian), Illinois, USA |
| 1 Mar 1981 |
| Archbishop Stephen Sulyk | Archbishop Emeritus of Philadelphia (Ukrainian), Pennsylvania, USA |
| 23 Jun 1984 |
| Marian Cardinal Jaworski | Archbishop Emeritus of Lviv |
| 15 Aug 1989 |
| Bishop Irynej Bilyk, O.S.B.M. | Bishop Emeritus of Buchach {Bučač} (Ukrainian) |
| 14 Oct 1990 |
| Bishop Miguel Mykycej, F.D.P. | Bishop Emeritus of Santa María del Patrocinio en Buenos Aires (Ukrainian), Argentina |
| 2 Mar 1991 |
| Bishop Markijan Trofym’yak | Bishop Emeritus of Lutsk |
| 4 Mar 1991 |
| Bishop Jan Purwinski | Bishop Emeritus of Kyiv-Zhytomyr |
| 28 May 1991 |
| Archbishop Jan Paweł Lenga, M.I.C. | Bishop Emeritus of Karaganda, Kazakhstan |
| 26 Apr 1992 |
| Archbishop Antonio Franco | Apostolic Nuncio Emeritus to Israel |
| 19 Sep 1993 |
| Bishop Mychajlo Koltun, C.SS.R. | Bishop of Sokal-Zhovkva (Ukrainian) |
| 12 Jul 1994 |
| Bishop Wasyl Ihor Medwit, O.S.B.M. | Auxiliary Bishop of Donets’k-Kharkiv (Ukrainian) |
| Most Junior |
| 9 Feb 2013 |
| Bishop Radosław Zmitrowicz, O.M.I. | Auxiliary Bishop of Kamyanets-Podilskyi |
| 12 Jan 2013 |
| Bishop Nil Yuriy Lushchak, O.F.M. | Auxiliary Bishop of Mukachevo (Munkács) (Ruthenian) |
| 5 Jan 2013 |
| Bishop Jacek Pyl, O.M.I. | Auxiliary Bishop of Odessa-Simferopol |
| 26 Aug 2012 |
| Bishop Borys Andrij Gudziak | Bishop of Saint Wladimir-Le-Grand de Paris (Ukrainian) |
| 18 Sep 2011 |
| Bishop Dmytro (Bohdan) Hryhorak, O.S.B.M. | Bishop of Buchach {Bučač} (Ukrainian) |
| 8 Dec 2010 |
| Bishop Jan Sobiło | Auxiliary Bishop of Kharkiv-Zaporizhia |
| 5 Sep 2010 |
| Bishop Venedykt (Valery) Aleksiychuk, M.S.U. | Auxiliary Bishop of Lviv (Ukrainian) |
| 18 Jun 2009 |
| Bishop Yosyf Milan, M.S.U. | Auxiliary Bishop of Kyiv-Halyč {Kiev} (Ukrainian) |
| 7 Apr 2009 |
| Archbishop Sviatoslav Shevchuk | Major Archbishop of Kyiv-Halyč {Kiev} (Ukrainian) |
| 20 Jul 2008 |
| Bishop Taras Senkiv, O.M. | Apostolic Administrator of Stryj (Ukrainian) |
| 3 May 2008 |
| Archbishop Petro Herkulan Malchuk, O.F.M. | Bishop of Kyiv-Zhytomyr |
| 7 Apr 2008 |
| Bishop Josaphat Oleh Hovera | Archiepiscopal Exarch of Lutsk (Ukrainian) |