Ordained Bishop | Years | Name | Current Title |
| Most Senior |
| 15 Aug 1954 |
| Eugênio Cardinal de Araújo Sales | Archbishop Emeritus of São Sebastião do Rio de Janeiro |
| 20 Jan 1957 |
| Archbishop Jaime Luiz Coelho | Archbishop Emeritus of Maringá, Parana |
| 22 Sep 1957 |
| Archbishop José Maria Pires | Archbishop Emeritus of Paraíba, Paraiba |
| 10 Nov 1957 |
| Bishop José Eugênio Corrêa | Bishop Emeritus of Caratinga, Minas Gerais |
| 13 Apr 1958 |
| Bishop José de Aquino Pereira | Bishop Emeritus of São José do Rio Preto, Sao Paulo |
| 10 Aug 1958 |
| Bishop Caetano Antônio Lima dos Santos, O.F.M. Cap. | Bishop Emeritus of Ilhéus, Baia |
| 7 May 1959 |
| Serafim Cardinal Fernandes de Araújo | Archbishop Emeritus of Belo Horizonte, Minas Gerais |
| 27 Mar 1960 |
| Bishop Epaminondas José de Araújo | Bishop Emeritus of Palmeira dos Índios, Alagoas |
| 25 Jul 1960 |
| Bishop Clemente José Carlos de Gouvea Isnard, O.S.B. | Bishop Emeritus of Nova Friburgo, Rio de Janeiro |
| 28 Aug 1960 |
| Archbishop Armando Círio, O.S.I. | Archbishop Emeritus of Cascavel, Parana |
| 29 Oct 1961 |
| Archbishop Antônio Ribeiro de Oliveira | Archbishop Emeritus of Goiânia, Goias |
| 6 Jan 1962 |
| Bishop José Mauro Ramalho de Alarcón Santiago | Bishop Emeritus of Iguatú, Ceara |
| Most Junior |
| 9 Jan 2010 |
| Bishop Egidio Bisol | Bishop of Afogados da Ingazeira, Pernambuco |
| 30 Dec 2009 |
| Bishop Otacílio Luziano Da Silva | Bishop of Catanduva, Sao Paulo |
| 27 Dec 2009 |
| Bishop Milton Kenan Júnior | Auxiliary Bishop of São Paulo, Sao Paulo |
| 28 Aug 2009 |
| Bishop Celso Antônio Marchiori | Bishop of Apucarana, Parana |
| 19 Jun 2009 |
| Bishop Henrique Soares da Costa | Auxiliary Bishop of Aracajú, Sergipe |
| 24 May 2009 |
| Bishop Edson Taschetto (Tasquetto) Damian | Bishop of São Gabriel da Cachoeira, Amazonas |
| 15 May 2009 |
| Bishop Rodolfo Luís Weber | Prelate of Cristalândia, Goias |
| 9 May 2009 |
| Bishop Bernardo Johannes Bahlmann, O.F.M. | Prelate of Óbidos, Para |
| 8 May 2009 |
| Bishop Giovane Pereira de Melo | Bishop of Tocantinópolis, Tocatins |
| 19 Apr 2009 |
| Bishop José Moreira Bastos Neto | Bishop of Três Lagoas, Mato Grosso do Sul |
| 18 Apr 2009 |
| Bishop Tarcísio Nascentes dos Santos | Bishop of Divinópolis, Minas Gerais |
| 29 Mar 2009 |
| Bishop José Valmor César Teixeira, S.D.B. | Bishop of Bom Jesus da Lapa, Baia |