| Date | Age | Event | Bishop | Title | Current Title |
| 15 Sep 2005 | 46.6 | Succeeded | Juan Maria Florindo Agurto Muñoz, O.S.M. | Bishop of San Carlos de Ancud |
| 75.4 | Retired | Juan Luis Ysern de Arce | Bishop of San Carlos de Ancud | Bishop Emeritus |
| 7 Jan 2006 | 57.6 | Appointed | Felipe Bacarreza Rodríguez | Bishop of Los Angeles | Bishop of Santa Maria de Los Angeles |
| 75.9 | Retired | Miguel Caviedes Medina | Bishop of Los Angeles | Bishop Emeritus |
| 4 Mar 2006 | 51.0 | Appointed | Bernardo Bastres Florence, S.D.B. | Bishop of Punta Arenas |
| 70.9 | Retired | Tomás Osvaldo González Morales, S.D.B. | Bishop of Punta Arenas | Bishop Emeritus |
| 25 Mar 2006 | 76.7 | Retired | Alberto Jara Franzoy | Bishop of Chillán | Bishop Emeritus |
| 47.7 | Appointed | Carlos Eduardo Pellegrín Barrera, S.V.D. | Bishop of Chillán |
| 6 Apr 2006 | 49.1 | Appointed | Fernando Natalio Chomalí Garib | Auxiliary Bishop of Santiago de Chile |
| 49.1 | Appointed | Fernando Natalio Chomalí Garib | Titular Bishop of Noba | Auxiliary Bishop of Santiago de Chile |
| 22 Apr 2006 | 51.2 | Ordained Bishop | Bernardo Bastres Florence, S.D.B. | Bishop of Punta Arenas |
| 29 Apr 2006 | 47.8 | Ordained Bishop | Carlos Eduardo Pellegrín Barrera, S.V.D. | Bishop of Chillán |
| 9 May 2006 | 97.2 | Died | Cirilo Polidoro Van Vlierberghe, O.F.M. † | Prelate Emeritus of Illapel |
| 3 Jun 2006 | 49.2 | Ordained Bishop | Fernando Natalio Chomalí Garib | Titular Bishop of Noba | Auxiliary Bishop of Santiago de Chile |
| 15 Sep 2006 | 78.8 | Retired | Angelo Sodano | Secretary of the Secretariat of State | Cardinal, Secretary Emeritus |
| 23 Oct 2006 | 42.0 | Appointed | Marco Antonio Órdenes Fernández | Bishop of Iquique |
| 18 Nov 2006 | 42.1 | Ordained Bishop | Marco Antonio Órdenes Fernández | Bishop of Iquique |
| 27 Dec 2006 | 65.0 | Appointed | Ricardo Ezzati Andrello, S.D.B. | Archbishop of Concepción (Santissima Concezione) |
| 79.5 | Retired | Antonio Moreno Casamitjana | Archbishop of Concepción (Santissima Concezione) | Archbishop Emeritus |
| 18 Apr 2007 | 69.8 | Died | Piero Biggio † | Apostolic Nuncio Emeritus to Denmark |
| 14 Sep 2007 | 91.4 | Died | José Manuel Santos Ascarza, O.C.D. † | Archbishop Emeritus of Concepción (Santissima Concezione) |
| 29 Oct 2007 | 61.0 | Appointed | Aldo Cavalli | Apostolic Nuncio to Colombia |
| 6 Dec 2007 | 55.5 | Appointed | Giuseppe Pinto | Apostolic Nuncio to Chile |
| 1 Mar 2008 | 81.2 | Appointed | Jorge Arturo Augustin Medina Estévez | Cardinal-Priest of S. Saba | Cardinal, Prefect Emeritus of the Congregation for Divine Worship and the Discipline of the Sacraments |
| 29 Jun 2008 | 97.1 | Died | Eladio Vicuña Aránguiz † | Archbishop Emeritus of Puerto Montt |
| 21 Sep 2008 | 87.3 | Died | Carlos González Cruchaga † | Bishop Emeritus of Talca |
| 4 Nov 2008 | 51.1 | Appointed | Pedro Ossandón Buljevic | Auxiliary Bishop of Concepción (Santissima Concezione) |
| 51.1 | Appointed | Pedro Ossandón Buljevic | Titular Bishop of La Imperial | Auxiliary Bishop of Concepción (Santissima Concezione) |
| 12 Dec 2008 | 51.2 | Ordained Bishop | Pedro Ossandón Buljevic | Titular Bishop of La Imperial | Auxiliary Bishop of Concepción (Santissima Concezione) |
| 20 Dec 2008 | 83.9 | Died | Gabriel Larraín Valdivieso † | Auxiliary Bishop Emeritus of Santiago de Chile |
| 7 Feb 2009 | 77.1 | Retired | Sixto José Parzinger Foidl, O.F.M. Cap. | Bishop of Villarrica | Bishop Emeritus |
| 46.7 | Appointed | Francisco Javier Stegmeier Schmidlin | Bishop of Villarrica |
| 19 Apr 2009 | 46.9 | Ordained Bishop | Francisco Javier Stegmeier Schmidlin | Bishop of Villarrica |
| 22 Sep 2009 | 64.8 | Appointed | Luigi Ventura | Apostolic Nuncio to France |