| Date | Age | Event | Bishop | Title | Current Title |
| 1 Apr 2005 | 47.4 | Appointed | Dieudonné Uringi Uuci | Bishop of Bunia |
| 18 Jun 2005 | 49.4 | Ordained Bishop | Vincent de Paul Kwanga Njubu | Bishop of Manono |
| 24 Jun 2005 | 47.7 | Ordained Bishop | Dieudonné Uringi Uuci | Bishop of Bunia |
| 23 Jul 2005 | 43.0 | Ordained Bishop | Fulgence Muteba Mugalu | Bishop of Kilwa-Kasenga |
| 27 Jul 2005 | 76.1 | Retired | Léon Lesambo Ndamwize | Bishop of Inongo | Bishop Emeritus |
| 67.4 | Appointed | Philippe Nkiere Keana, C.I.C.M. | Bishop of Inongo |
| 1 Oct 2005 | 88.0 | Died | Matthieu Kanyama † | Bishop Emeritus of Kabinda |
| 9 Oct 2005 | 62.9 | Died | Charles Kambale Mbogha, A.A. † | Archbishop of Bukavu |
| 7 Jan 2006 | 49.9 | Appointed | Pierre-Célestin Tshitoko Mamba | Bishop of Luebo |
| 25 Mar 2006 | 50.1 | Ordained Bishop | Pierre-Célestin Tshitoko Mamba | Bishop of Luebo |
| 26 Apr 2006 | 49.7 | Appointed | François-Xavier Maroy Rusengo | Archbishop of Bukavu |
| 3 May 2006 | 75.7 | Retired | Godefroid Mukeng'a Kalond, C.I.C.M. | Archbishop of Kananga | Archbishop Emeritus |
| 31 May 2006 | 75.3 | Retired | Louis Mbwôl-Mpasi, O.M.I. | Bishop of Idiofa | Bishop Emeritus |
| 18 Jun 2006 | 49.8 | Installed | François-Xavier Maroy Rusengo | Archbishop of Bukavu |
| 11 Aug 2006 | 81.7 | Died | Alphonse-Marie Runiga Musanganya † | Bishop Emeritus of Mahagi-Nioka |
| 9 Dec 2006 | 51.6 | Appointed | Marcel Madila Basanguka | Archbishop of Kananga |
| 6 Jan 2007 | 76.1 | Died | Frédéric Etsou-Nzabi-Bamungwabi, C.I.C.M. † | Cardinal, Archbishop of Kinshasa |
| 26 Mar 2007 | 44.4 | Appointed | Philibert Tembo Nlandu, C.I.C.M. | Coadjutor Bishop of Budjala |
| 31 Mar 2007 | 78.2 | Retired | Jérôme Nday Kanyangu Lukundwe | Bishop of Kongolo | Bishop Emeritus |
| 42.3 | Appointed | Oscar Ngoy wa Mpanga, C.S.Sp. | Bishop of Kongolo |
| 25 Apr 2007 | 42.2 | Appointed | Willy Ngumbi Ngengele, M. Afr. | Bishop of Kindu |
| 23 May 2007 | 75.1 | Retired | Ignace Matondo Kwa Nzambi, C.I.C.M. | Bishop of Molegbe | Bishop Emeritus |
| 3 Jun 2007 | 44.6 | Ordained Bishop | Philibert Tembo Nlandu, C.I.C.M. | Coadjutor Bishop of Budjala |
| 9 Jun 2007 | 42.5 | Ordained Bishop | Oscar Ngoy wa Mpanga, C.S.Sp. | Bishop of Kongolo |
| 22 Jun 2007 | 86.5 | Died | Jacques Mbali † | Bishop Emeritus of Buta |
| 22 Jul 2007 | 42.4 | Ordained Bishop | Willy Ngumbi Ngengele, M. Afr. | Bishop of Kindu |
| 6 Dec 2007 | 68.2 | Appointed | Laurent Monsengwo Pasinya | Archbishop of Kinshasa |
| 10 Dec 2007 | 64.0 | Appointed | Francisco-Javier Lozano | Apostolic Nuncio to Romania |
| 64.0 | Appointed | Francisco-Javier Lozano | Apostolic Nuncio to Moldova, Republic of | Apostolic Nuncio to Romania |
| 2 Feb 2008 | 68.3 | Installed | Laurent Monsengwo Pasinya | Archbishop of Kinshasa |
| 1 Mar 2008 | 85.6 | Appointed | Lorenzo Antonetti | Cardinal-Priest of S. Agnese in Agone | Cardinal, President Emeritus of the Administration of the Patrimony of the Apostolic See |
| 51.6 | Appointed | Léon Kalenga Badikebele | Apostolic Nuncio to Ghana |
| 51.6 | Appointed | Léon Kalenga Badikebele | Titular Archbishop of Magnetum | Apostolic Nuncio to Ghana |
| 5 Mar 2008 | 93.6 | Died | Gastone Mojaisky-Perrelli † | Archbishop Emeritus of Sant’Angelo dei Lombardi-Conza-Nusco-Bisaccia, Italy |
| 18 Mar 2008 | 48.9 | Appointed | Etienne Ung'eyowun Bediwegi | Bishop of Bondo |
| 1 May 2008 | 51.8 | Ordained Bishop | Léon Kalenga Badikebele | Titular Archbishop of Magnetum | Apostolic Nuncio to Ghana |
| 8 Jun 2008 | 49.2 | Ordained Bishop | Etienne Ung'eyowun Bediwegi | Bishop of Bondo |
| 31 Jul 2008 | 66.0 | Appointed | Jean-Pierre Tafunga, S.D.B. | Coadjutor Archbishop of Lubumbashi |