Ordained Bishop | Years | Name | Current Title |
| Most Senior |
| 8 Oct 1981 |
| Archbishop Donald James Reece | Archbishop Emeritus of Kingston in Jamaica |
| 25 Jan 1984 |
| Adam Joseph Cardinal Maida | Archbishop Emeritus of Detroit, Michigan, USA |
| 23 Mar 1985 |
| Manuel Cardinal Monteiro de Castro | Major Penitentiary Emeritus of the Apostolic Penitentiary, Roman Curia |
| 19 Oct 1985 |
| Archbishop Eugenio Sbarbaro | Apostolic Nuncio |
| 8 Sep 1989 |
| Bishop Michel Marie Jacques Dubost, C.I.M. | Bishop Emeritus of Evry-Corbeil-Essonnes, France |
| 22 Jan 1990 |
| Archbishop Robert Rivas, O.P. | Archbishop Emeritus of Castries, Saint Lucia |
| 5 Apr 1990 |
| Archbishop Giacinto Berloco | Apostolic Nuncio |
| 15 Sep 1995 |
| Bishop Robert Joseph Kurtz, C. R. | Bishop Emeritus of Hamilton in Bermuda |
| 10 Feb 1996 |
| Archbishop Charles Henry Dufour | Archbishop Emeritus of Kingston in Jamaica |
| 27 Jun 1996 |
| Emil Paul Cardinal Tscherrig | Apostolic Nuncio |
| 9 Jul 1996 |
| Archbishop Allen Henry Vigneron | Archbishop Emeritus of Detroit, Michigan, USA |
| 6 Jan 1997 |
| Archbishop Luigi Pezzuto | Apostolic Nuncio |
| Most Junior |
| 25 Jul 2024 |
| Bishop Kendrick John Forbes | Bishop of Roseau, Dominica |
| 9 Jul 2023 |
| Bishop Philippe Médard Guiougou | Bishop of Basse-Terre (et Pointe-ŕ-Pitre), Guadeloupe |
| 6 Feb 2022 |
| Bishop Alain René Ransay | Bishop of Cayenne (Cajenna), French Guyana |
| 11 Jun 2021 |
| Bishop Neil Sebastian Ricardo Scantlebury | Bishop of Bridgetown, Barbados |
| 19 Sep 2020 |
| Bishop John Derek Persaud | Bishop of Mandeville, Jamaica |
| 29 Jul 2017 |
| Bishop Clyde Martin Harvey | Bishop of Saint George’s in Grenada |
| 10 Jun 2017 |
| Archbishop Santiago De Wit Guzmán | Apostolic Nuncio to Trinidad and Tobago |
| 20 Feb 2016 |
| Bishop Gerard Maximin County, C.S.Sp. | Bishop of Kingstown, Saint Vincent and Grenadines |
| 24 Jan 2016 |
| Bishop Karel Marinus Choennie | Bishop of Paramaribo, Suriname |
| 1 Oct 2015 |
| Bishop Wiesław Śpiewak, C. R. | Bishop of Hamilton in Bermuda |
| 12 Apr 2015 |
| Archbishop David Thomas Daniel Macaire, O.P. | Archbishop of Fort-de-France (e Saint Pierre), Martinique |
| 14 Sep 2013 |
| Bishop Robert Anthony Llanos | Bishop of Saint John’s-Basseterre, Virgin Islands (British) |