| Diocese | Type | Date Vacant | Last Bishop | Event |
|---|---|---|---|---|
| Campo Maior, Piaui | Diocese | 9 Apr 2025 | Francisco de Assis Gabriel dos Santos, C.Ss.R. | Appointed, Bishop of Cajazeiras, Paraiba |
| Januária, Minas Gerais | Diocese | 13 Apr 2025 | Geraldo de Souza Rodrigues † | Died |
| Jardim, Mato Grosso do Sul | Diocese | 30 Oct 2024 | João Gilberto de Moura | Appointed, Bishop of Lins, Sao Paulo |
| Nova Friburgo, Rio de Janeiro | Diocese | 25 Feb 2025 | Luiz Antônio Lopes Ricci | Appointed, Bishop of Itapetininga, Sao Paulo |
| Paranaguá, Parana | Diocese | 20 May 2025 | Edmar Perón | Resigned |
| Propriá, Sergipe | Diocese | 14 Feb 2025 | Vítor Agnaldo de Menezes | Appointed, Archbishop of Vitória da Conquista, Bahia |
| Rubiataba-Mozarlândia, Goias | Diocese | 28 May 2025 | Francisco Agamenilton Damascena | Appointed, Bishop of Luziânia, Goias |
| Sorocaba, Sao Paulo | Archdiocese | 7 Mar 2025 | Júlio Endi Akamine, S.A.C. | Appointed, Coadjutor Archbishop of Belém do Pará |
| Teixeira de Freitas-Caravelas, Bahia | Diocese | 25 Feb 2025 | Jailton de Oliveira Lino, P.S.D.P. | Appointed, Bishop of Itabuna, Bahia |
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